RESEARCH OF MINERAL ADSORBENTS APPLICATION FOR WATER-ALCOHOL SOLUTIONS PURIFICATION IN TECHNOLOGY OF ALCOHOLIC BEVERAGES
Abstract
The possibility of using natural mineral adsorbents - clinoptilolite and schungite - in the adsorption purification of water-alcohol solutions of different concentrations was studied using the example of impurities of ethanol of acetaldehyde and ethyl acetate. The feasibility of studying the above-mentioned minerals for the adsorption of simple organic substances is justified. The best concentration of a water-alcohol solution for adsorption of acetaldehyde 80-85 vol.%, ethyl acetate-40 vol.% is experimentally established. The rational duration of phase contact for adsorption of acetaldehyde is from 10 to 20 minutes, for adsorption of ethyl acetate - 5 minutes.
An explanation for the dependence of the sorption efficiency on the ethanol content in a water-alcohol solution is proposed based on the known dependencies of the rectification factor on the ethanol concentration. The larger the rectification factor, the less the hydrogen bond of this impurity with ethanol and the easier it is to sorb it from ethanol by mineral adsorbents. The practical and economic feasibility of using the mineral adsorbent clinoptilolite of Ukrainian origin in the preparation of alcoholic beverages instead of imported active coal is shown. It is determined that to purify water-alcohol solutions from aldehydes, which most worsen the taste of alcoholic beverages, it is more expedient to use clinoptilolite as an adsorbent. It is shown that the use of clinoptilolite for the preparation of vodkas from non-standard rectified alcohol will improve the tasting indicators of the final product.Keywords
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Xiao, P., Zhang, J., Webley, P., Li, G., Singh, R., Todd, R. (2008). Capture of CO2 from flue gas streams with zeolite 13X by vacuum-pressure swing adsorption. Adsorption, 14 (4-5), 575–582. doi: 10.1007/s10450-008-9128-7
Li, Y., Yi, H., Tang, X., Li, F., Yuan, Q. (2013). Adsorption separation of CO2/CH4 gas mixture on the commercial zeolites at atmospheric pressure. Chemical Engineering Journal, 229, 50–56. doi: 10.1016/j.cej.2013.05.101
Farag, H. A. A., Ezzat, M. M., Amer, H., Nashed, A. W. (2011). Natural gas dehydration by desiccant materials. Alexandria Engineering Journal, 50 (4), 431–439. doi: 10.1016/j.aej.2011.01.020
Lively, R. P., Chance, R. R., Kelley, B. T., Deckman, H. W., Drese, J. H., Jones, C. W., Koros, W. J. (2009). Hollow Fiber Adsorbents for CO2Removal from Flue Gas. Industrial & Engineering Chemistry Research, 48 (15), 7314–7324. doi: 10.1021/ie9005244
Bezdieniezhnykh, L. Ya., Aleksieieva, T. M. (2009). Mozhlyvosti adsorbtsiinoho ochyshchennia stichnykh vod vid ioniv vazhkykh metaliv. Ekolohichna bezpeka, 2 (6), 54–57.
Nechytailo, L. Ya., Ersteniuk, H. M. (2015). Efektyvnist vykorystannia pryrodnoho sorbentu dlia ochyshchennia pytnoi vody vid nitrat-yoniv. Naukovi zapysky TNPU. Seriya:Khimiya, 22, 24–28.
Luchian, C. E., Colibaba, C., Niculaua, M., Codreanu, M., Cotea, V. V. (2015). Innovative materials in winemaking. BIO Web of Conferences, 5, 02023. doi: 10.1051/bioconf/20150502023
Melnyk, V. M., Melnyk, V. P., Mank, V. V. et. al. (2002). Pat. No. 51497 UA. Sposib deghidrataciyi etylovogho spyrtu. MPK А7 C07С7/13. No. 2002042978; declareted: 12.04.2002; published: 15.11.2002, Bul. No. 11.
Mineral'ni resursy Ukrayiny (2014). Kyiv: Derzhavne naukovo-vyrobnyche pidpryyemstvo «Derzhavnyy informatsiynyy heolohichnyy fond Ukrayiny», 270.
Tekhnicheskaya dokumentaciya. Zakarpatskiy ceolitovyi zavod. Available at: http://www.dpzzz.com/ru/docs.htm
Shushkov, D. A., Kotova, O. B., Naumko, I. M. (2011). Svoystva i primenenie klinoptilolitovyih tufov Zakarpatya i analtsimsoderzhaschih porod Timana. Zapiski Ukrayinskogo mineralogichnogo tovaristva, 8, 226–229.
Ambrozova, P., Kynicky, J., Urubek, T., Nguyen, V. (2017). Synthesis and Modification of Clinoptilolite. Molecules, 22 (7), 1107. doi: 10.3390/molecules22071107
Bakakyn, V. V., Seriоtkyn, Yu. V. (2009). Unificirovannye formul'nye i ob"emnye harakteristiki v sravnitel'noy kristallohimii prirodnyh ceolitov. Zhurnal strukturnoi khymii, 50 (7), 123–130.
Hrechanovskaia, E. E. (2010). Metrika elementarnoi yacheiky i otnoshenye Si/Al v tseolytakh riada heilandyt-klynoptylolyt Sokyrnytskoho mestorozhdenyia (Zakarpate, Ukrayna). Mineralohichnyi zhurnal, 32 (4), 12–22.
Ignatov, I., Mosin, O. V. (2014). The structure and composition of carbonaceous fullerene containing mineral shungite and microporous crystalline aluminosilicate mineral zeolite. Mathematical model of interaction of shungite and zeolite with water molecules. Advances in Physics Theories and Applications, 28, 10–21.
Yanchevskyi, V. K., Oliynychuk, S. T., Kravchuk, Z. D. et. al. (2002). Tablicy spirtometricheskie. Kyiv: UkrNYYspyrtbyoprod, 592.
Instrukciya po tekhnologhicheskomu i mikrobyologhicheskomu kontrolyu spirtovogho proizvodstva (2008). Moscow: VNIIPBT, 399.
Carev, N. Y., Carev, V. Y., Katrakov, Y. B. (2000). Praktycheskaya gazovaya khromatoghrafiya. Barnaul: AGhU, 156.
DSTU 4222:2003. Natsional'nyi standart Ukrayiny. Horilky, spyrt etylovyi ta vodno-spyrtovi rozchyny. Hazokhromatohrafichnyi metod vyznachannya vmistu mikrokomponentiv (2004). Kyiv: Derzhspozhyvstandart Ukrayiny, 12.
DSTU 4221:2003. Spyrt etylovyi rektyfikovanyi. Tekhnichni umovy (2004). Kyiv: Derzhspozhyvstandart Ukrayiny, 10.
Tseolit. Available at: https://sokirnitskij-tseoltovij-zavod.prom.ua/g6619229-tseolt
Aktivirovannyi ugol (marka BAU-A, BAU-MF, DAK, OU-A). Available at: http://snabhim.com.ua/vodoochistka/aktivirovannyj-ugol-bau-a.html?gclid=CjwKEAjwqcHLBRCq5uHTpLL12FISJAD6PgDIDGKtUzxLGaueJyUVFM-58u-Xr-c-xE2-msM7QO8J-xoC8Mjw_wcB
Zhang, K., Lively, R. P., Noel, J. D., Dose, M. E., McCool, B. A., Chance, R. R., Koros, W. J. (2012). Adsorption of Water and Ethanol in MFI-Type Zeolites. Langmuir, 28 (23), 8664–8673. doi: 10.1021/la301122h
Kontar, O. Ya., Valievakhin, H. M., Haleiev, E. R., Dokhov, O. I. (2014). Pat. No. 105707 UA. Sposib otrymannia spyrtu etylovoho znevodnenoho. MPK А7 C07С7/13. No. a201300030; declareted: 02.01.2013; published: 10.02.2014, Bul. No. 11.
S. Onuki, J. A Koziel, J.(Hans) van Leeuwen, W. S. Jenks, D. Grewell, L. Cai. (2008). Ethanol production, purification, and analysis techniques: a review. 2008 Providence, Rhode Island. doi: 10.13031/2013.25186
Nguyen, C. M., Reyniers, M.-F., Marin, G. B. (2010). Theoretical study of the adsorption of C1–C4 primary alcohols in H-ZSM-5. Physical Chemistry Chemical Physics, 12 (32), 9481–9493. doi: 10.1039/c000503g
Marynchenko, V. P., Marynchenko, L. V., Fil, O. V. (2014). Ochyshchennia vodno-spyrtovykh rozchyniv vid vyshchykh spyrtiv mineralnymy adsorbentamy. Naukovi pratsi NUKhT, 20 (5), 214–219.
DOI: http://dx.doi.org/10.21303/2461-4262.2017.00397
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